Chemical EquilibriumHard

Question

For a cell reaction involving a two-electron change, the standard e.m.f. of the cell is found to be 0.295 V at 25oC. The equilibrium constant of the reaction at 25oC will be

Options

A.29.5 × 10-2
B.10
C.1 × 1010
D.1 × 10-10

Solution

The equilibrium constant is related to the standard emf of cell by the expression
log K = E0cell × = 0.295 ×
log K = = 10 or K = 1 × 10-10

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