NEET | 2018Chemical BondingHard

Question

The bond dissociation energies of X2, Y2 and XY are in the ratio of 1 : 0.5 : 1. H for the formation of XY is –200 kJ mol–1. The bond dissociation energy of X2 will be

Options

A.

200 kJ mol–1

B.

100 KJ mol-1

C.

800 kJ mol–1

D.

400 kJ mol-1

Solution

let B.E. of x2 , y2 & xy are x kJ mol–1 , 0.5x kJ mol–1 and x kJ mol–1 respectively
12X2+12Y2XY ;H=-200 kJ mol-1H=-200=(B.E)Reactant-(B.E)Product=12(X)+12(0.5X)-1×(X)
B.E of X2 = x = 800 kJ mol–1

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