JEE Main | 2018Aromatic HydrocarbonsHard
Question
The combustion of benzene (l) gives CO2(g) and H2O(l). Given that heat of combustion of benzene at constant volume is -3263.9 kJ mol-1 at 25oC ; heat of combustion (in kJ mol-1) of benzene at constant pressure will be - (R = 8.314 JK-1 mol-1)
Options
A.
- 452.46
B.
3260
C.
-3267.6
D.
4152.6
Solution
C6H6() + O2(g) 6CO2(g) + 3H2O()
ng = 6 - 7.5 = - 1.5 (change in gaseous mole)
U or E = - 3263.9 kJ
H = U + ngRT
ng = - 1.5
R = 8.314 JK-1 mol-1
T = 298 K
So H = - 3263.9 + (-1.5) 8.314 10-3 298
= - 3267.6 kJ
H = Heat at constant pressure
U / E = Heat at constant volume
R = gas constant
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