NEET | 2017Chemical BondingHard

Question

Pick out the correct statement with respect to [Mn(CN)6]3 –:-

Options

A.

It is sp3d2 hybridised and tetrahedral

B.

It is d2sp3 hybridised and octahedral

C.

It is dsp2 hybridised and square planar

D.

It is sp3d2 hybridised and octahedral

Solution

[Mn(CN)6]3- → O.S. of Mn is (+3)
C.N.=6
Mn+3 →3d4 →
Presence of SFL (Pairing is possible)
[d2sp3, octahedral]
   t2g               eg

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