JEE Advanced | 2015Chemical BondingHard

Question

Under hydrolytic conditions, the compounds used for preparation of linear polymer and for chain termination, respectively, are

Options

A.CH3SiCl3 and Si(CH3)4
B.(CH3)2SiCl2 and (CH3)3SiCl
C.(CH3)2SiCl2 and CH3SiCl3
D.SiCl4 and (CH3)3SiCl

Solution

(A) CH3 SiCl3 Cross linked polymer
Si(CH3)4 → NOT hydrolysed
(B) (CH3)2 SiCl2

(C) (CH3)2SiCl2 linear polymer formation
CH3SiCl3 Cross linked polymer
(D) SiCl4 H4SiO4 + 4HCl

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