AIPMT | 2015Chemical Kinetics and Nuclear ChemistryHard

Question

Cobalt (III) chloride forms several octahedral complexes with ammonia. Which of the following will not give test of chloride ions with silver nitrate at 25oC ?

Options

A.CoCl3 . 4NH3
B.CoCl3 . 5NH3
C.CoCl3 . 6NH3
D.CoCl3 . 3NH3

Solution

CoCl3 . 3NH3 ⇒ [Co(NH3)3Cl3]
[Co(NH3)3Cl3] no ppt

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