Atomic StructureHardBloom L2
Question
The electron in a hydrogen atom makes a transition from an excited state to the ground state. Which of the following statements is true?
Options
A.Its kinetic energy increases, and its potential and total energies decrease.
B.Its kinetic energy decreases, its potential energy increases, and its total energy remains the same.
C.Its kinetic and total energies decrease, and its potential energy increases.
D.Its kinetic, potential, and total energies all decrease.
Solution
{"given":"An electron in hydrogen transitions from an excited state (quantum number $n > 1$) to the ground state ($n = 1$). In Bohr's model: $$KE_n = \\frac{13.6}{n^2} \\text{ eV}, \\quad PE_n = -\\frac{27.2}{n^2} \\text{ eV}, \\quad E_n = -\\frac{13.6}{n^2} \\text{ eV}$$","key_observation":"As $n$ decreases (excited → ground state), $KE_n \\propto \\frac{1}{n^2}$ increases (positive), while $PE_n \\propto -\\frac{1}{n^2}$ becomes more negative (decreases), and total energy $E_n \\propto -\\frac{1}{n^2}$ also becomes more negative (decreases).","option_analysis":[{"label":"(A)","text":"Kinetic energy increases; potential and total energies decrease.","verdict":"correct","explanation":"When $n$ decreases from an excited state to the ground state, $KE = \\frac{13.6}{n^2}$ eV increases. Both $PE = -\\frac{27.2}{n^2}$ eV and $E = -\\frac{13.6}{n^2}$ eV become more negative, meaning they decrease."},{"label":"(B)","text":"Kinetic energy decreases; potential energy increases; total energy remains the same.","verdict":"incorrect","explanation":"Kinetic energy actually increases as $n$ decreases, and total energy also changes (becomes more negative); it does not remain constant."},{"label":"(C)","text":"Kinetic and total energies decrease; potential energy increases.","verdict":"incorrect","explanation":"Kinetic energy increases (not decreases) when transitioning to a lower energy level; potential energy becomes more negative, so it decreases, not increases."},{"label":"(D)","text":"Kinetic, potential, and total energies all decrease.","verdict":"incorrect","explanation":"Kinetic energy increases as $n$ decreases; only potential energy and total energy decrease (become more negative)."}],"answer":"(A)","formula_steps":[]}
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