ThermodynamicsHard

Question

Benzene burns according to the following equation at 300 K (R = 8.314 J mole-1K-1)
     2C6H6(l) + 15 O2 (g)  → 12 CO2 (g) + 6H2O(l)     ᐃHo = - 6542 kJ/mol
What is the ᐃEo for the combustion of 1.5 mol of benzene

Options

A.-3271 kJ
B.-9813 kJ
C.-4906.5 kJ
D.None of these

Solution

From given reaction ᐃng = 12 - 15 = - 3
so ᐃEo = ᐃHo - ᐃng RT = - 6542 + 3RT       
for 1.5 mole, ᐃEo = {-6542 + 3RT}  = 4912.11 KJ

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