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Question

A solute′S′ undergoes a reversible trimerization when dissolved in a certain solvent. The boiling point elevation of its 0.1 molal solution was found to be identical to the boiling point elevation in case of a 0.08 molal solution of a solute which neither undergoes association nor dissociation. To what percent had the solute ′S′ undergone trimerization?

Options

A.30%
B.40%
C.50%
D.60%

Solution

3S ⇋ S3
1-α      α/3    ⇒ i = 1 -
Now     0.1 = 0.08
⇒  α = 0.3. Hence 30% trimerization.

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