SolutionHard

Question

Consider two liquids A & B having pure vapour pressures PAo & PBo forming an ideal solution. The plot of v/s (where XA and YA are the mole fraction of liquid A in liquid and vapour phase respectively) is linear with slope and Y intercepts respectively :

Options

A.
B.
C.
D.

Solution

P′A = PAo XA and P′B = PoB XB  
P′A = PM . YA and P′B = PM .YB
∴   
or         or      (1 - YA) = PoB - PoB XA
or    + (PoB - PoA)     or  
or     y = mx + C   ∴  Slope = m = and intercept C =

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