Coordination CompoundHard
Question
On adding AgNO3 solution to a solution of [Pt(NH3)3Cl3]Cl, the percentage of total chloride ion precipitated is:
Options
A.100
B.75
C.50
D.25
Solution
[Pt(NH3)3Cl3]Cl 
[Pt(NH3)3Cl3]+ (aq) + Cl- (aq)
Out of four Cl- only one Cl- (i.e. 25%) present in ionization sphere will give preciptate.
Ag+ + Cl- → AgCl ↓ (white).
[Pt(NH3)3Cl3]+ (aq) + Cl- (aq)Out of four Cl- only one Cl- (i.e. 25%) present in ionization sphere will give preciptate.
Ag+ + Cl- → AgCl ↓ (white).
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