Coordination CompoundHard
Question
Isomerism exhibited by [Cr(NH3)2(H2O)2Cl2]+ are :
Options
A.ionisation, optical
B.ionisation, optical
C.geometrical, optical
D.coordination, geometrical
Solution
(A) No ionisation isomerism because the counter anion is absent.
(B) No hydrate isomerism because the counter anion is absent.
(C) Ma2b2c2 - 5 (aa)(bb)(cc) (optically inactive)
(aa)(bc)(bc) (optically inactive)
(bb)(ac)(ac) (optically inactive)
(cc)(ab)(ab) (optically inactive)
(ab)(ac)(bc) (optically active)
(B) No hydrate isomerism because the counter anion is absent.
(C) Ma2b2c2 - 5 (aa)(bb)(cc) (optically inactive)
(aa)(bc)(bc) (optically inactive)
(bb)(ac)(ac) (optically inactive)
(cc)(ab)(ab) (optically inactive)
(ab)(ac)(bc) (optically active)
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