Coordination CompoundHard

Question

Of the following configurations, the optical isomers are :
              

Options

A.I and II
B.I and III
C.II and IV
D.II and III

Solution

(A) I and II are geometrical isomers (i.e. cis - and trans isomers)
(B) I and III are identical structures (both are trans-isomers having plane of symmetry)
(C) II and IV are mirror images of each other and are non-super imposable.
(D) II and III are geometrical isomers (i.e. cis - and trans isomers)

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