Ionic EquilibriumHard

Question

The pH of a solution obtained by mixing 100 ml of 0.2 M CH3COOH with 100 ml of 0.2 M NaOH would be :
(pKa for CH3COOH = 4.74)

Options

A.4.74
B.8.87
C.9.10
D.8.57

Solution

    CH3COOH + OH-  CH3COO- + H2O
t = 0         20             20
t = eq        -               -             20
So,    [CH3COO-] = = 0.1 M
pH = 7 +   pKa + log C = 7 + 2.37 + log 10-1 = 7 + 2.37 - 0.5 = 8.87

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