Ionic EquilibriumHard

Question

Slaked lime, Ca(OH)2 is used extensively in sewage treatment. What is the maximum pH that can be established in Ca(OH)2 (aq):
    Ca(OH)2 (s) ⇋ Ca2+ (aq) + 2OH- (aq) ; KSP = 5.5 × 10-6

Options

A.1.66
B.12.35
C.7.0
D.14.0

Solution

KSP of Ca(OH)2 = 4s3 = 5.5 × 10-6
∴    s = 3= 1.11 × 10-2
∴  [OH-] = 2s = 2 × 1.11 × 10-2
∴  pOH = 1.65    ∴   pH = 12.35   

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