Chemical Kinetics and Nuclear ChemistryHard
Question
Following reaction can take place in both direction A 
B,
It is given that for the forward reaction :
and for the backward reaction
[B] Rate
0.01 M 1 × 10-2 Ms-1
0.02 M 2 × 10-2 Ms-1
Hence, net reaction rate of B is :
B, It is given that for the forward reaction :
and for the backward reaction
[B] Rate
0.01 M 1 × 10-2 Ms-1
0.02 M 2 × 10-2 Ms-1
Hence, net reaction rate of B is :
Options
A.= k1 [A] - k2 [B]
B.= k1 - k2 [B]
C.= k1 [A] - k2
D.= k1 - k2
Solution
Rate of reaction independent of conc. of A
Net Rxn Rate = K1 [A]0 - K2[B]1
order wrt B is 1 because rate doubles when conc. of B doubles,
then Net Rxn Rate = k1 - k2 [B].
Net Rxn Rate = K1 [A]0 - K2[B]1
order wrt B is 1 because rate doubles when conc. of B doubles,
then Net Rxn Rate = k1 - k2 [B].
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