For the cell (at 298 K) Ag(s) | AgCl(s) | Cl- (aq) || AgNO3 (aq) | Ag(s) Which of following is correct -

NEETElectrochemistryHard

Question

For the cell (at 298 K) Ag(s) | AgCl(s) | Cl^- (aq) || AgNO₃ (aq) | Ag(s)
Which of following is correct -

A.The cell emf will be zero when [Ag⁺]_a = [Ag⁺]_c ([Ag⁺] in anodic compartment = [Ag⁺] in cathodic compartment)

B.The amount of AgCl(s) precipitate in anodic compartment will decrease with the working of the cell.

C.The concentration of [Ag+] = constant, in anodic compartment during working of cell.

D.E_cell = E^o_Ag⁺/Ag - E^oCl-|AgCl|Ag -

E_Cell = E^o_Cell - ; At [Ag⁺]_c = [Ag⁺]_a equilibrium will achieve and K = K_sp = [Ag⁺]_a[Cl^-]_a

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