ElectrochemistryHard

Question

Calculate the value of Λm for SrCl2 in water at 25oC from the following data :
Conc. (mol/lt)            0.25           1
Λm-1 cm2 mol-1)    260        250

Options

A.270
B.260
C.250
D.255

Solution

Λm = Λm - b√c
260 = Λm - 0.5 b    ........ (1)
250 = Λm - b    ........ (2)
On solving (1) & (2), we get
Λm - = 270 Ω-1 cm2 mol-1

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