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Question

Elevation in b.p. of an aqueous urea solution is 0.52o. (Kb = 0.52o mol-1 kg) Hence, mole-fraction of urea in this solution is :

Options

A.0.982
B.0.567
C.0.943
D.0.018

Solution

As    ᐃTb = molality × Kb
        0.52 = m × 0.52
        molality = 1 mol kg-1
∴       urea = 1 mol
moles of water = = 55.55
mole fraction of urea = = 0.018

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