Analytical ChemistryMedium
Question
Given below are certain cations. Using inorganic qualitative analysis, arrange them in increasing group number from 0 to VI.
A. ${Al}^{3 +}$
B. ${Cu}^{2 +}$
C. ${Ba}^{2 +}$
D. ${Co}^{2 +}$
E. ${Mg}^{2 +}$
Choose the correct answer from the options given below.
Options
A.$E,C,D,B,A$
B.$E,A,B,C,D$
C.$B,A,D,C,E$
D.$B,C,A,D,E$
Solution
Sol. [Key Concept: Classical cation analysis groups]
In the classical qualitative analysis scheme used here, Cu²⁺ belongs to Group II, Al³⁺ to Group III, Co²⁺ to Group IV, Ba²⁺ to Group V and Mg²⁺ to Group VI. Their increasing order is therefore B, A, D, C, E, option (3). These group numbers refer to analytical separation groups.
| Group | Cations |
|---|---|
| Group-II | $${Cu}^{2 +}$$ |
| Group-III | $${Al}^{3 +}$$ |
| Group-IV | $${Co}^{2 +}$$ |
| Group-V | $${Ba}^{2 +}$$ |
| Group-VI | $${Mg}^{2 +}$$ |
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