Carbonyl CompoundMedium

Question

Match List I with List II.

List I (Reaction) List II(Reagents/Condition)
A. I.
B. II. $\ {CrO}_{3}$
C. III. ${KMnO}_{4}/KOH,\Delta$
D. IV. (i) $O_{3}$(ii) $Zn - H_{2}O$

Choose the correct answer from the options given below:

Options

A.A-IV, B-I, C-II, D-III
B.A-I, B-IV, C-II, D-III
C.A-IV, B-I, C-III, D-II
D.A-III, B-I, C-II, D-IV

Solution

Sol. [Key Concept: Reagents for common organic transformations]

A–IV: reductive ozonolysis cleaves the C=C bond to give two cyclohexanone molecules. B–I: benzoyl chloride with anhydrous AlCl₃ acylates benzene to benzophenone. C–II: CrO₃ oxidises cyclohexanol to cyclohexanone. D–III: hot alkaline KMnO₄ oxidises the ethyl side chain to potassium benzoate. Therefore, option (1).

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