d and f-Block ElementsMedium

Question

Given below are two statements:

Statement I : Ferromagnetism is considered as an extreme form of Para magnetism.

Statement II : The number of unpaired electrons in a ${Cr}^{2 +}$ ion $(Z = 24)$ is the same as that of a ${Nd}^{3 +}$ ion $(Z = 60)$.

In the light of the above statements, choose the correct answer from the options given below :

Options

A.Both Statement I and Statement II are true
B.Both Statement I and Statement II are false
C.Statement I is true but Statement II is false
D.Statement I is false but Statement II is true

Solution

Sol. [Key Concept: Assertion–Reason — ferromagnetism as an extreme form of paramagnetism; unpaired electrons] Substances which are attracted very strongly in applied magnetic field are termed as ferromagnetic. In fact, ferromagnetism is an extreme form of para magnetism.

Hence statement I is correct.

$${Cr}^{2 +} = 3{\text{ }d}^{4}4{\text{ }s}^{0} $$Unpaired electrons = 4

$${Nd}^{3 +} = 4f^{3}6{\text{ }s}^{0} $$Unpaired electrons $= 3$

Hence, Statement II is incorrect

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