HydrocarbonsMedium

Question

Match List I with List II:

List I (TrAns.ition metal/compound/ complex) List II (Catalytic Role)
A. $$V_{2}O_{5}$$ I. Preparation of ammonia from $N_{2}/H_{2}$ mixture
B. Fe II. Polymerization of alkynes
C. $${PdCl}_{2}$$ III. Preparation of $H_{2}{SO}_{4}$ and ${SO}_{2}$
D. Ni complex IV. Oxidation of ethyne to ethanal

Choose the correct Ans. from the options given below.

Options

A.A-III, B-IV, C-I, D-II
B.A-IV, B-I, C-III, D-II
C.A-II, B-I, C-IV, D-III
D.A-III, B-I, C-IV, D-II

Solution

Sol. [Key Concept: Matching name-reactions / reagents with products] A.

$V_{2}O_{5} \rightarrow$ Catalyses the oxidation of ${SO}_{2}$ into ${SO}_{3}$ in the manufacture of $H_{2}{SO}_{4}$. (III)

B. $Fe \rightarrow$ Act as catalysts in preparation of ammonia from $N_{2}/H_{2}$ mixture. (I)

C. ${PdCl}_{2} \rightarrow$ Oxidation of ethyne to ethanal. (IV)

D. Ni complex → Polymerization of alkynes. (II)

A → III, B → I, C → IV, D → II

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