IsomerismMedium

Question

Given below are two statements:

Statement-I : 2, 6-diethylcyclohexanone and 6-methyl-2-n-propylcyclohexanone are metamers.

Statement-II : 2, 2, 6, 6-tetramethylcyclohexanone exhibits keto-enol tautomerism.

In the light of the above statements, choose the correct answer from the options given below.

Options

A.Both Statement-I and Statement-II are true.
B.Both Statement-I and Statement-II are false.
C.Statement-I is true but Statement-II is false.
D.Statement-I is false but Statement-II is true.

Solution

Sol. [Key Concept: The two ketones are metamers (same group, different alkyls on either side); $2,2,6,6$-tetramethyl ketone has no $\alpha$-H so no keto-enol tautomerism — Statement-I true, Statement-II false.]

Statement-I is correct and Statement-II is incorrect

are metamers

No Keto enol tautomerism

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