d and f-Block ElementsMedium

Question

Pairs of elements with the same number of electrons in their respective 4f orbital are

[Atomic number, Eu-63, Gd-64, Dy-66, Ho-67,

Tm-69, Yb-70, Lu-71, Hf-72]

A. (Eu and Gd)

B. (Dy and Ho)

C. ( Yb and Hf )

D. ( Lu and Tm)

Choose the correct answer from the options given below:

Options

A.B and C Only
B.A and B Only
C.A and D Only
D.A and C Only

Solution

Sol. [Key Concept: Write the configurations: Eu and Gd are both $4f^{7}$, and Yb and Hf are both $4f^{14}$ — so the matching pairs are A and C.]

$${Gd - \lbrack Xe\rbrack 4f^{7}5{\text{ }d}^{1}6{\text{ }s}^{2} }{Eu - \lbrack Xe\rbrack 4f^{7}6{\text{ }s}^{2} }$$Dy $- \lbrack Xe\rbrack 4f^{10}6{\text{ }s}^{2}$

$${Ho - \lbrack Xe\rbrack 4f^{11}6{\text{ }s}^{2} }{Hf - \lbrack Xe\rbrack 4f^{14}6{\text{ }s}^{2}5{\text{ }d}^{2} }{Yb - \lbrack Xe\rbrack 4f^{14}6{\text{ }s}^{2} }{Lu - \lbrack Xe\rbrack 4f^{14}5{\text{ }d}^{1}6{\text{ }s}^{2} }{Tm - \lbrack Xe\rbrack 4f^{13}6{\text{ }s}^{2} }$$

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