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Question

Given below are two statements:

Statement-I : and

are two anomers of D-(+)-glucose.

Statement-II : The open chain forms of D-glucose and D-fructose contain three similar chiral carbons at $C_{3},C_{4}$ and $C_{5}$.

In the light of the above statements, choose the correct answer from the options given below:

Options

A.Both Statement-I and Statement-II are true.
B.Both Statement-I and Statement-II are false.
C.Statement-I is true but Statement-II is false.
D.Statement-I is false but Statement-II is true.

Solution

Sol. [Key Concept: The two ring structures differ only at the anomeric $C_{1}$ ($\alpha$- and $\beta$-D-glucose); glucose and fructose share identical configurations at $C_{3},C_{4},C_{5}$.]

α-D-Glucose and β-D-Glucose are anomers.

At C-3, C-4 and C-5 are identical configuration in glucose and fructose.

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