Redox and Equivalent ConceptMedium
Question
In order to oxidise a mixture of 1 mole each of ${FeC}_{2}O_{4},{Fe}_{2}\left( C_{2}O_{4} \right)_{3},{FeSO}_{4}$ and ${Fe}_{2}\left( {SO}_{4} \right)_{3}$ in acidic medium, the number of moles of ${KMnO}_{4}$ required is :
Options
A.3
B.2
C.5
D.7
Solution
Sol. [Key Concept: Equivalents of ${KMnO}_{4} = \sum$ equivalents of the reductants; moles $\times 5 =$ total milli-equivalents.]
Meq of ${KM}_{n}O_{4} = meq$ of ${FeC}_{2}O_{4} + meq$ of ${Fe}_{2}\left( C_{2}O_{4} \right) +$ meq of ${FeSO}_{4}$
moles $\times 5 = 1 \times 3 + 1 \times 6 + 1 \times 1$
moles $= \frac{10}{5} = 2$
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