MetallurgyHardBloom L3

Question

Formation of metallic copper from the sulphide ore in the commercial thermo-metallurgical process essentially involves which one of the following reactions:

Options

A.Cu2S + O2 → Cu2O + SO2 ; CuO + C → Cu + CO
B.Cu2S + O2 → Cu2O + SO2 ; 2Cu2O + Cu2S → 6Cu + SO2
C.Cu2S + 2O2 → CuSO4 ; CuSO4 + Cu2S → 3Cu + 2SO2
D.Cu2S + O2 → Cu2O + SO2 ; Cu2O + CO → 2Cu + CO2

Solution

Sol. Copper undergo self/auto reduction reaction :-

Cu2S + O2 → Cu2O + SO2

2 Cu2O + CuS → 6 Cu + SO2

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