Coordination CompoundHardBloom L1
Question
Which of the following statement(s) is/are incorrect
Options
A.In [CoBrCl(en)2]+ geometrical isomerism exists, while optical isomerism does not exist
B.
Potassium aquadicyanidosuperoxidoperoxidochromate(III) is IUPAC name for
K2[Cr(CN)2O2(O2)(H2O)]
C.
There are 3 geometrical isomers and 15 stereoisomers possible for
[Pt(NO2)(NH3)(NH2OH)(py)]+ and [PtBr ClI (NO2)(NH3)(py)] respectively
D.cis and trans forms are not diastereomers to each other
Solution
Sol. (A) [COBrCl(en)2]+
(B) K2[Cr(CN)2O2(O2)(H2O)]
Potassium aquadicyanidosuperoxidoperoxidochromate (II)
(C) [Pt(NO2)(NH3)(NH2OH)(Py)]+ ⇒ 3-geometrical isomers
[PtBrCl I(NO2)(NH3)(Py)] ⇒ 30-stereoisomers
(D) cis and Trans are diastereo-isomers.
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