MetallurgyHard

Question

It is noticed that ${Pb}^{2 +}$ is more stable than ${Pb}^{2 +}$ but ${Sn}^{2 +}$ is less stable than ${Sn}^{4 +}$. Observe the following reactions

Options

A.
B.
C.
D.

Solution

${PbO}_{2} + Pb \rightarrow 2PbO$

${Pb}^{2 +}$ is more stable hence reaction will be spontaneous. So $\Delta G^{\circ}\ _{r}(1)$ is negative.

$${SnO}_{2} + Sn \rightarrow 2SnO $$${Sn}^{+ 2}$ is less stable, so reaction will be nonspontaneous hance $\Delta G^{\circ}\ _{r}(2)$ is positive.

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