Alkyl Halides and Aryl HalidesHard

Question

The correct order of the rate of reaction of the following reactants with nucleophile by $S_{N}1$ mechanism is :

(Given : Structure I and II are rigid)

Options

A.IV $<$ III $<$ II $<$ I
B.III $<$ I $<$ II $<$ IV
C.II $<$ I $<$ III $<$ IV
D.I $<$ II $<$ III $<$ IV

Solution

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