Alkyl Halides and Aryl HalidesHard

Question

The correct order of the rate of the reaction for the following reaction with respect to nucleophiles is:

$${CH}_{3}Br + {Nu}^{\Theta} \longrightarrow {CH}_{3}Nu + {Br}^{\Theta} $$(1) ${PhO}^{-} > - \ ^{-}OH > {CH}_{3}{COO}^{-} > {ClO}_{4}^{-}$

Options

A.${PhO}^{-} > - \ ^{-}OH > {CH}_{3}{COO}^{-} > {ClO}_{4}^{-}$
B.${ClO}_{4}^{-} > {CH}_{3}{COO}^{-} > \ ^{-}OH > {PhO}^{-}$
C.${CH}_{3}{COO}^{-} > {PhO}^{-} > \ ^{-}OH > {ClO}_{4}^{-}$
D.$\ ^{-}OH > {PhO}^{-} > {CH}_{3}{COO}^{-} > {ClO}_{4}^{-}$

Solution

Stability order of anion

nucleophilicity order reverse of stability of anion

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