ElectrochemistryHard

Question

Lactic acid, HC3H5O3, produced in 1 g sample of muscle tissue was titrated using phenolphthalein as indicator against OH ions which were obtained by the electrolysis of water. As soon as OH ions are produced, they react with lactic acid and at complete neutralization, immediately a pink colour is noticed. If electrolysis was made for 1158 s using 50.0 mA current to reach the end point, what was the percentage of lactic acid in muscle tissue?

Options

A.5.4%
B.2.7%
C.10.8%
D.0.054%

Solution

$n_{eq}HC_{3}H_{5}O_{3} = n_{OH^{-}} = \frac{Q}{F}$

$\text{Or, }\frac{w}{90} \times 1 = \frac{50 \times 10^{- 3} \times 1158}{96500} \Rightarrow w = 0.054\text{ gm} $$$\therefore\text{\% of lactice acid = }\frac{0.054}{1} \times 100 = 5.4\%$$

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