Nitrogen Containing CompoundHard

Question

Which of the following amines will not give N2 gas on treatment with nitrous acid (NaNO2 + HCl) ?

Options

A.C2H5NH2
B.CH2NH2
C.(CH3)2CHNH2
D.All will give N2

Solution

All aliphatic primary amines librate N2 on treatment with nitrous acid (NaNO2 + NCl) RNH2 + HONO → R - OH + N2 + H2O

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