ElectrochemistryHard

Question

The limiting molar conductivities ∧o for NaCl, KBr and KCl are 126, 152 and 150 S cm2 mol-1 respectively. The ∧o for NaBr is

Options

A.128 S cm2 mol-1
B.302 S cm2 mol-1
C.278 S cm2 mol-1
D.176 S cm2 mol-1

Solution

oNaCl = λoCl = 126 .....(1)
oKBr = λoK++ λoBr- = 152 .....(2)
oKCl = λoK++ λoCl- = 150 .....(3)
oNaBr = λoNa + λoBr-
oNaBr = 126 + 152 - 150 = 128

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