NEET | 2018Carboxylic Acid and Acid DerivativesHard

Question

Carboxylic acid have higher boiling points than aldehydes, ket ones an d even alcoh ols of comparable molecular mass. It is due to their

Options

A.

formation of intramolecular H-bonding

B.

formation of carboxylate ion

C.

more extensive association of carboxylic acid via van der Waals force of attraction

D.

formation of intermolecular H-bonding.

Solution

Carboxylic acid has higher boiling point than aldehyde, ketone and even alcohols of comparable molecular mass. This is due to more extensive association through intermolecular H-bonding.

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