JEE Main | 2018Carbonyl CompoundHard

Question

At 518oC, the rate of decomposition of a sample of gaseous acetaldehyde, initially at a pressure of 363 Torr, was 1.00 Torr s-1 when 5% had reacted and 0.5 Torr s-1 when 33% had reacted. The order of the reaction is :

Options

A.

3

B.

1

C.

0

D.

2

Solution

CH3CHO CH4 + CO
r1 = 1 torr sec-1 , when 5% reacted (95% unreacted)
r2 = 0.5 torr sec-1 , when 33% reacted (67% unreacted)
r (a - x)m    m = order of reaction
          a-x = unreacted
r1r2=(a-x1)a-x2m
10.5=0.950.67m
2 = (1.41)m  2 = 2m
 m = 2

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