JEE Main | 2018Carbonyl CompoundHard
Question
At 518oC, the rate of decomposition of a sample of gaseous acetaldehyde, initially at a pressure of 363 Torr, was 1.00 Torr s-1 when 5% had reacted and 0.5 Torr s-1 when 33% had reacted. The order of the reaction is :
Options
A.
3
B.
1
C.
0
D.
2
Solution
CH3CHO CH4 + CO
r1 = 1 torr sec-1 , when 5% reacted (95% unreacted)
r2 = 0.5 torr sec-1 , when 33% reacted (67% unreacted)
r (a - x)m m = order of reaction
a-x = unreacted
2 = (1.41)m 2 =
m = 2
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