JEE Main | 2018Chemical EquilibriumEasy
Question
An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constants for the formation of HS- from H2S is 1.0 10-7 and that of S2- from HS- ions is 1.2 10-13 then the concentration of S2- ions in aqueous solution is :
Options
A.
3Â Â 10-20
B.
6Â Â 10-21
C.
5Â Â 10-19
D.
5Â Â 10-8
Solution
[H2S] = 0.10 M
[HCl] = 0.20 M [H+] = 0.2 M
(1) H2S HS- + H+ K1 = 1.0 10-7
(2) HS S2- + H+ K2 = 1.2 10-13
So,
H2S S2- + 2H+ K1 K2
= 1.2 10-20
So, [S2-] =
= 3 10-20 M
All the [H+] will come from strong acid [HCl] only.
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