ThermochemistryHard

Question

Consider the following reactions :
   C (s) + O2 (g) → CO2 (g) + x kJ
   CO (g) + O2 (g) → CO2 (g) + y kJ
The heat of formation of CO (g) is :

Options

A.- (x + y) kJ / mol
B.(x - y) kJ / mol
C.(y - x) kJ / mol
D.None of these

Solution

C(s) + O2(g) → CO2(g);
      ᐃrH1 = - x kJ/mol    .....(1)
CO(g) + 1/2O2(g) → CO2(g)
ᐃH2 = - y kJ/mole   so,   C(s) + O2 (g) → C(g) ᐃH = y - x

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