Nitrogen Containing CompoundHard

Question

p-chloroaniline and anilinium hydrochloride can be distinguished by:

Options

A.Sandmeyer reaction
B.NaHCO3
C.AgNO3
D.Carbylamine test

Solution

No white ppt.
White ppt. (AgCl)
The halogen atom of A is directly attached to benzene ring and C - C bond acquires partial double bond character due to lp-π electron interaction, so not claned easily.

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