Coordination CompoundHard

Question

Match List-I (Complexes) with List-II (Hybridization) of central atom and select the correct answer using the codes given below the lists :
    List-I                List-II
A Ni(CO)4             1. sp3
B [Ni(CN)4]2-        2. dsp2
C [Fe(CN)6]4-        3. sp3d2
D [MnF6]4-             4. d2sp3

Options

A.A → 1
B → 3
C → 2
D → 4
B.A → 5
B → 2
C → 4
D → 3
C.A → 5
B → 3
C → 2
D → 4
D.A → 1
B → 2
C → 4
D → 3

Solution

[Ni(CO)4] = sp3 ; [Ni(CN)4]2- = dsp2 ; [Fe(CN)6]4- = d2sp3 ; [MnF6]4- = sp3d2.

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