Coordination CompoundHard

Question

What will be the theoretical value of ′spin only′ magnetic moment when Fe(SCN)3 reacts with a solution containing F- ions to yield a colourless complex ?

Options

A.2.83 B.M.
B.3.87 B.M
C.5.92 B.M.
D.1.73 B.M.

Solution

[Fe(SCN)(H2O)5]2+ [FeF6]3-, F- being weak ligand Fe3+ - . Therefore, five
unpaired electrons and so μ = B.M. ≈ 5.92.

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