Coordination CompoundHard

Question

Which of the following is non-conducting ?

Options

A.CoCl3.6NH3
B.CoCl3.5NH3
C.CoCl3.4NH3
D.CoCl3.3NH3

Solution

(A) CoCl3 6NH3 [Co(NH3)6]3++ 3Cl- (no. of ions = 4 & total electrical charges = 6)
(B) CoCl3.5NH3 [Co(NH3)5 Cl]2+ + 2Cl-  (no. of ions = 3 & total electrical charges = 4)
(C) CoCl3.4NH3 [Co(NH3)4 Cl2]+ + Cl-  (no. of ions = 2 & total electrical charges = 2)
(D) CoCl3.3NH3 [Co(NH3)3 Cl3] (neutral solution). It will not conduct electricity.

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