MetallurgyHard

Question

On the basis of ellingham diagram which of the following is/are correct.

Options

A.Entropy change for all metal oxides is roughly same.
B.Below the boiling point, ′TᐃS′ factor is same irrespective of metal.
C.Above ᐃG = 0 line, oxide decomposes into metal & oxygen.
D.If randomness increases the slope increases

Solution

(A) = - ᐃS, is slope in Ellingham diagram. Which is same below the boiling point.
(B) Below the boiling point slope is same as factor TᐃS is same.
(C) Above ᐃG = 0 line free energy becomes positive so oxide decomposes.
(D) Random increases i.e. ᐃS increases, so slope also increases.

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