Analytical ChemistryHard

Question

Consider the following observation :
Mn+ + HCl (dilute) → white precipitate water soluble yellow precipitate.
The metal ion Mn+ will be :

Options

A.Hg2+
B. Ag+
C.Pb2+
D.Sn2+

Solution

Pb2+ + 2Cl- →  PbCl2 ↓ (soluble in hot water) ; PbCl2 + CrO42- →  PbCrO4 ↓ (yellow) + 2Cl-.

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