s-Block ElementsHard

Question

Which of the following disproportionate(s) on heating with sodium hydroxide ?

Options

A.P4
B.S8
C.Cl2
D.B.

Solution

(A) P4 + 3 NaOH + 3 H2O →  PH3 + 3 NaH2PO2
(B) 4S + 6 NaOH Na2S2O3 + 2 Na2S + 3 H2O
(C) 3 Cl2 + 6 NaOH  → 5 NaCl + NaClO3 + 3 H2O
(D) 2B + 6 NaOH → 2 Na3BO3 + 3 H2

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