ElectrochemistryHard

Question

An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to

Options

A.Increasing in ionic mobility of ions
B.100% ionisation of electrolyte at normal dilution
C.increase in both , ie, number of ions and ionic mobility of ions
D.increase in number of ions

Solution

λeq = k × V =
On dilution, the number of current carrying particles per cm decreases but the volume of solution increases. Consequently, the ionic solution increases, which on turns increases the equivalent conductance of strong electrolyte.

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