Aromatic HydrocarbonsHard

Question

The reaction of the toluene with Cl2 in presence of FeCl3 gives ′X′ and reaction in presence of light gives ′Y′. Thus ′X′ and ′Y′ are

Options

A.X = Benzal chloride, Y = o-chlorotoluene
B.X = m-chlorotoluene, Y = p-chlorotoluene
C.X = o-and p-chlorotoluene, Y = trichloromethyl benzene
D.X = Benzyl chloride, Y = m-chlorotoluene

Solution

In the presence of halogen carrier, electophilic substitution occurs while in the presence of sunlight substitution occurs at the side chain.

(∵ -CH3 is an o/p directing group.)

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