PolymerHard

Question

Which one of the following does not exhibit the phenomenon of mutarotation ?

Options

A.(+) Sucrose
B.(+) Lactose
C.(+) Maltose
D.(–) Fructose

Solution

Reducing sugars that exist in hemiacetal and hemiketal forms, undergo mutarotation in aqueous solution.
Among the given carbohydrates, only sucrose is a non-reducing sugar as in it the hemiacetal and hemiketal groups of glucose and fructose are linked together through O-atom and thus, not free. Due to the absence of free hemiacetal or hemiketal group, sucrose does not exhibit mutarotation.

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