Coordination CompoundHard
Question
NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic).The coordination geometries of Ni2+ in the paramagnetic and diamagnetic states are respectively
Options
A.tetrahedral and tetrahedral
B.square planar and square planar
C.tetrahedral and square planar
D.square planar and tetrahedral
Solution
In both complexes Ni exists as Ni2+.
In sp3 (tetrahedral)
In dsp2 (square planar geometry)
In sp3 (tetrahedral)
In dsp2 (square planar geometry)
Create a free account to view solution
View Solution FreeMore Coordination Compound Questions
The oxidation sate of iron in Na4[Fe(CN)5(NOS)] is...Which of the following statements is false?...The purple colour of KMnO4 is due to the transition...Among the following metal carbonyls, the C - O bond order is lowest in...Which of the following pairs will show the same magnetic moment (′spin only′)?...